乙二胺

规格:
CAS: 107-15-3
产品编号: HXWJ0000000368
MDL: MFCD00008204
品牌: Bellen
Chemical NameEthylenediamine
Synonym 1,2-diaminoethane beta-Aminoethylamine ?-Aminoethylamine NCI-C60402 Ethylenamin α,ω-Ethanediamine 1,2-Ethandiamin {h 1,2-Diamino-ethaan ethane-1,2-diamine 乙二胺 EDA,, 1,2-二氨基乙烷,1,2-乙二胺,乙亚胺,双酮嗪,亚胺-154,抗癌-161 抗癌-161 ethylene diamine 1,2-diamino-ethane β-Aminoethylamine 乙亚胺 amerstat274 Edamine 1,4-Diazabutane 1,2-DIAMINOETHANE 双酮嗪 Diaminoethane C2H8N2 (ethane-1,2-diamine) Dimethylenediamine Ethylendiamine 乙二胺(无水) EDA 乙二胺 溶液 乙烯二胺 1,2-二氨基乙烷
CAS Number107-15-3
PubChem Substance ID3301
EC Number203-468-6
Beilstein Registry Number605263
MDL NumberMFCD00008204
Merck Number3795
Chemical Name Translation乙二胺
Wiswesser Line NotationZ2Z
InChIInChI=1S/C2H8N2/c3-1-2-4/h1-4H2
GHS Symbol
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1295,1935

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 730 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalatio

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CHTPBA Chimica Therapeutica.  (Paris, France)  V.1-8, 1965-73.  For
   publisher information, see EJMCA5.  Volume(issue)/page/year: 4,136,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1200 mg/kg
TOXIC EFFECTS :
   Behavioral - ataxia
REFERENCE :
   MTPEEI Meditsina Truda i Promyshlennaya Ekologiya.  Industrial Medicine and
   Ecology. (Mezhdunarodnaya Kniga, ul.B. Yakimanka, 39 117049 Moscow, Russia)
   No.1-    1993-  Volume(issue)/page/year: (1),38,1997

TYPE OF TEST            :

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 33 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 3200 mg/kg
SEX/DURATION            : female 6-13 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   7,29,1987

WGK Germany2
Hazard Codes C
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H318 Causes serious eye damage 严重伤害眼睛
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H302+H332
    Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    RTECSKH8575000
    Precautionary statements
    • P342+P311
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P305+P351+P338
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P303+P361+P353
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P370+P378
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      Signal word Danger
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
      • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
        UN Number 1604 UN1604 UN 1604 8/PG 2
        Risk Statements
        • R10 Flammable 易燃
        • R42/43
        • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
        • R34 Causes burns 会导致灼伤
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition Flammables area 充氩保存 Air Sensitive 密封避光阴凉处保存。充氩保存 密封避光阴凉处保存。 密封阴凉处保存。
          Packing Group
          Hazard Class8
          Restrict 易制爆危险化学品
          Warnings 危化品目录(2015)
        • Used as fuel additives, bleach activators, chelating agents, and corrosion inhibitors.
        • {ALD} Merck:14,3795
        • {ALF} At high temperatures, reduces nitroarenes to azo-compounds. Reaction does not occur for nitro-compounds with o-substituents or p-amino-substituents: J. Org. Chem., 49, 1215 (1984).
        • {A
        • {uni_hamburg} Short: II/14a
        • {uni_hamburg} Short: II/25B
        • {ALFA} The ethylenediamine complex of Cr2+ reduces aryl bromides to the hydrocarbons. For an example, see: Org. Synth. Coll., 6, 821 (1988).
        • {ALF} The Li derivative in excess amine is a strong base for the rearrangement of primary allylic alcohols to the isomeric aldehydes in high yield: J. Chem. Soc., Chem. Commun., 812 (1985).
        • {SNA}
        • 107-15-3 HXWJ0000000368 	乙二胺

          化学属性

          Mol. FormulaNH2CH2CH2NH2
          Mol. Weight60.10
          Refractive indexn20/D 1.4565(lit.)
          Boiling Point118 °C(lit.)
          Density0.899 g/mL at 25 °C(lit.)
          Melting Point8.5 °C (lit.)
          Flash Point38°(100°F)
          Solubility溶于水、醇,不溶于苯,微溶于乙醚。
          TSCAYes
          Autoignition Point716 °F
          Vapor Density2.07 (vs air)
          Vapor Pressure10 mmHg ( 20 °C)
          Stability对空气、湿度敏感
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