甲胺水溶液

规格:
CAS: 74-89-5
产品编号: HXYJ0000018671
MDL: MFCD00008104
品牌: Bellen
Chemical NameMethylamine
Synonym methylamine(non-specificname) Methylamin 一甲胺 MERCURIALIN Monomethylamine CH3NH2 Carbinamine aminomethane AMINE C1 氨基甲烷 MMA-50 氨基甲烷水溶液 monomethylamine ....% N-methylamine MMA 一甲胺(无水) methylamine (mono) 甲胺水溶液 AMINOMETHANE AKOS BBS-00004243 ai3-15637-x 甲胺 溶液 Mercurialin MONOMETHYLAMINE methanamine 甲基胺水溶液 伯胺 氨基甲烷醇溶液 anhydrousmethylamine 氨基甲烷水溶液,一甲胺,甲胺溶液 氨基甲烷溶液 methylamine(solutions) Methylaminen Metyloamina 甲胺,醇溶液 甲胺,2M/甲醇 甲胺 甲胺水溶液/甲胺醇溶液 氨基甲烷水溶液,甲胺溶液 Metilamine METHYLAMINE METHANOL 甲胺,2M/四氢呋喃 methylamine(mono) 甲胺, 40% 水溶液 氨基甲烷;混甲胺;一甲胺;伯胺 甲胺水溶液(40%) 混甲胺 Methanamine Monomethylamin ....% METHYLAMINE MMA-40 甲胺, 40% W/W AQ. SOLN. Aminomethan 甲胺醇溶液 一甲胺(40%) Aminomethane 甲胺醇溶液 ,一甲胺,伯胺 Methylamine
MDL NumberMFCD00008104
CAS Number74-89-5
Beilstein Registry Number741851
EC Number200-820-0
PubChem Substance ID6329
Merck Number14,6014
Chemical Name Translation甲胺(易制爆)
Wiswesser Line NotationZ1
InChIInChI=1S/CH5N/c1-2/h2H2,1H3
GHS Symbol
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2400 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,81,1982

TYPE OF TEST            : LD5

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem.

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 2400 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 3 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 174,285,1986

TYPE OF TEST            : Dominant lethal test
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 10 ug/m3
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 46(5),7,1981

WGK Germany2
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H370 Causes damage to organs 导致器官损伤
  • H351 Suspected of causing cancer 怀疑致癌
    Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US) Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    RTECSPF6300000
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P305+P351+P338
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P301+P310
    • P370+P378
    • P403+P235
    • P303+P361+P353
    • P304+P340+P310
      Signal word Danger
      Safety Statements
      • S29 Do not empty into drains 不要排入下水道;
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
      • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
      • S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处;
      • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
      • S3 Keep in a cool place 保存在阴凉处;
      • S7 Keep container tightly closed 保存在严格密闭容器中;
      • S33 Take precautionary measures against static discharges 对静电采取预防措施;
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
        Packing GroupII
        UN Number UN2924 1235 UN1235 UN 3286 3/PG 2
        Risk Statements
        • R12 Extremely flammable 极端易燃
        • R20 Harmful by inhalation 吸入有害
        • R19 May form explosive peroxides 可能生成易爆的过氧化物质
        • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
        • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
        • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
        • R11 Highly flammable 非常易燃
        • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
        • R37 Irritating to respiratory system 刺激呼吸道
        • R34 Causes burns 会导致灼伤
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
        • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
          Hazard Codes Xn;F+ 3 F+,Xn,C,F,T F,T F,C F,Xn
          Hazard Class3
          Storage condition 安瓿或气瓶盛装阴凉保存。 Flammables area 2-8℃ 2-8℃ 安瓿或气瓶盛装阴凉保存。充氩保存
          Warnings 危化品目录(2015)
        • 分解产物为氨,属低毒类,具有刺激性和腐蚀性。
        • 氨中的一个氢被甲基取代后所形成的衍生物。甲胺是最简单的伯胺。
        • ⑴、甲胺水溶液或醇溶液均为易燃液体。由于闪点低,易挥发,有毒,和空气会形成爆炸性混合物,避免日光照射和使用易发生静电的装置。甲胺对铜或铜合金、铝、锡和镀锌铁板有腐蚀性。易燃。
        • ⑵、化学性质具有伯胺的典型反应:
        • ① 水溶液呈碱性,与无机酸、有机酸、酸性芳香族硝基化合物等作用生成具有一定熔点的盐。与铜、银等重金属氯化物生成络盐。
        • ② 与酰氯、酸酐等发生酰基化反应,生成N-取代酰胺。与羧酸生成的盐再经脱水
        • 有机合成。有机溶剂。
        • {uni_hamburg} Short: II/14a
        • Title: Molecular Constants: Diamagnetic Molecules
        • Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E.
        • Editor: Hellwege, K.-H.; Hellwege, A.M.
        • Source: Landolt-B?rnstein, New Series
        • Volume: II/14a
        • Page: 1-788
        • Year: 1982
        • Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy
        • ISBN: 3-540-11365-7
        • ISBN: 978-3-540-11365-2
        • Internet Resource: DOI:10.1007/b19966
        • RefComment: 196 figs., XI
        • {uni_hamburg} Short: II/19b
        • Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules
        • Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G.
        • Editor: Hüttner, W.
        • Source: Landolt-B?rnstein, New Series
        • Volume: II/19b
        • Year: 1992
        • Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy
        • ISBN: 3-540-54578-6
        • ISBN: 978-3-540-54578-1
        • Internet Resource: DOI:10.1007/b44334
        • RefComment: XI, 488 pages.
        • Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
        • {uni_hamburg} Short: II/19c
        • Title: Molecular Constants: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Constants of Diamagnetic Molecules
        • Author: Demaison, J.; Hüttner, W.; Tiem
        • 74-89-5 HXYJ0000018671 	甲胺水溶液

          化学属性

          Mol. FormulaCH3NH2
          Mol. Weight31.06
          Density0.785 g/mL at 25 °C
          Autoignition Point806 °F
          Vapor Density1.08 (20 °C, vs air)
          Boiling Point40 °C
          Vapor Pressure10.86 psi ( 55 °C)
          Melting Point-93.5°C
          Refractive indexn20/D 1.360-1.372
          Flash Point-14°(6°F)
          TSCAYes
          Solubility易溶于水,溶于乙醇、乙醚等。
          Stability对光和热敏感
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